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14.3.4.1 Deacylation/Reacylation Reactions. In many cases, the initially synthesized phospholipids do not have the appropriate fatty acids in the 1 - and 2positions of the glycerol backbone. As noted earlier, phosphatidic acid usually has palmitate or stearate in the 1-position and linoleate or oleate in the 2-position. Remodeling reactions are therefore required to introduce arachidonic acid into the 2-position of PC, PE, and PI, where it is then available for mobilization to initiate eicosanoid synthesis. In the lung, type I1 pneumocytes utilize remodeling reactions to generate dipalmitoylphosphatidylcholine (dipalmitoyllecithin), the major lipid component of pulmonary surfactant. Remodeling is initiated by the action of a phospholipase A2, which removes the fatty acid from the 2-position of the phospholipid, generating the corresponding lysophospholipid. There are two mechanisms for reacylating the lysophospholipid: direct acylation, which uses fatty acyl-CoA as the fatty acid donor, and transacylation, in which the fatty acid that acylates the lysophospholipid is taken from another phospholipid in a transesterification reaction. install barcode font excel 2007 [SOLVED] Generate barcode in excel free - Spiceworks Community
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